Nanoconfinement of lithium borohydride in Cu-MOFs towards low temperature dehydrogenation.

نویسندگان

  • Weiwei Sun
  • Shaofeng Li
  • Jianfeng Mao
  • Zaiping Guo
  • Huakun Liu
  • Shixue Dou
  • Xuebin Yu
چکیده

Successful synthesis and investigation of a new material that uses copper-metal-organic frameworks (Cu-MOFs) as the template for loading LiBH(4) are reported. The nanoconfinement of LiBH(4) in the pores of Cu-MOFs results in an interaction between LiBH(4) and Cu(2+) ions, enabling the LiBH(4)@Cu-MOFs system to achieve a much lower dehydrogenation temperature than pristine LiBH(4).

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عنوان ژورنال:
  • Dalton transactions

دوره 40 21  شماره 

صفحات  -

تاریخ انتشار 2011